Mechanisms of stress corrosion cracking and intergranular attack in alloy 600 in. Investigating a mechanism for transgranular stress. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. Carbonate stress corrosion cracking acscc is a common problem in the oil and gas production, petroleum refining, and petrochemicalchemical processing industries. The stress corrosion cracking scc of aluminum alloys is a welldocumented phenomenon, but there is considerable disagreement in the scientific literature as to what mechanism causes it. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism.
Review and survey of alkaline carbonate stress corrosion. Amine cracking typically occurs on the surface and the cracks are usually radially projected from seton nozzles. Corrosion mechanism in aqueous solution has been amply demonstrated. Stress corrosion cracking and hydrogen cracking are two important forms of environmental cracking which can cause serious failures in the oil and gas, pipeline, process and many other industries. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Stress corrosion cracking results from the conjoint action of three components. Stress corrosion cracking scc is a significant ageing degradation mechanism for major components of both pressurized water reactors pwrs and boiling water reactors bwrs. The postulated mechanisms for stress corrosion cracking of. The interaction of corrosion fatigue and stresscorrosion. Microstructural aspects, which included residual stress state, phase distribution, phase ratio, and microhardness, were related to the propensity for scc crack initiation in different simulated. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. A study on the mechanism of stress corrosion cracking of duplex stainless steels in hot alkalinesulfide solution. Stress corrosion cracking is the growth of crack formation in a corrosive environment.
Acscc is a form of alkaline stress corrosion cracking that often occurs more aggressively at higher ph and high concentrations of carbonate solutions. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Polythionic acid stress corrosion cracking deterioration. Amine cracking is often intertwined with wet hydrogen sulfide h 2 s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine treating systems. This excludes corrosionreduced sections that fail by fast fracture. Corrosion mechanism an overview sciencedirect topics.
The fourth mode of cracking is alkaline stress corrosion cracking ascc. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Alkaline carbonate scc failures at a refinery springerlink. The most obvious differences between the two forms are the temperature sensitivity of highph scc, the fracture morphology, and the ph of the pi pe environment. This technical committee report is issued by nace international under the auspices of stg 34. Corrosion engineering is the field dedicated to controlling and preventing corrosion in the most common use of the word, this means. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The stress corrosion cracking scc and the electrochemical behavior of an api x70 pipeline steel in a simulated acidic soil solution were investigated using slow strain rate testing ssrt. The primary cause of scc is the residual stress created in the component during manufacturing or fabrication. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. Nace sp0403 avoiding caustic stress corrosion cracking of.
Temperature is a significant environmental factor affecting cracking. It requires a susceptible material and, depending on the material, sufficient levels of. In atmospheric corrosion which also exemplifies uniform corrosion, a very thin layer of electrolyte is present. Corrosion is a natural process that converts a refined metal into a more chemicallystable form such as oxide, hydroxide, or sulfide. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfidecontaining solutions has been useful for material selection in many. Carbonate cracking is a form of alkaline stress corrosion cracking that occurs. The importance of a conjoint action of corrosion and stress as well as the nature of. Intergranular intercrystalline corrosion is selective attack. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem.
This is an important mechanism which produces failure in a metal. Corrosionpedia what is stress corrosion cracking scc. It is caused by a combination of material properties now recognized as affecting mostly high strength alloys, it occurs in part under high tensile strength and the grain structure of the material. Corrosion mechanism of pure aluminium in aqueous alkaline. Cscc can attack highly resistant austenitic stainless steel. Stress corrosion cracking scc can be defined as the penetration and. Structural failure due to scc is often sudden and unpredictable, occurring after as little as a few hours of exposure, or after months or even years of satisfactory service. If the thickness of the oxide layer changed linearly with potential then we would expect the anodic current to be independent of potential. The failure mechanism for both fractured components a pipe and a heat exchanger tube was alkaline carbonate stress corrosion cracking. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Control of alkaline stress corrosion cracking in pressurized. This paper details the visual, semeds, metallographic, and microhardness evaluations. Likewise, some gas scrubbing units are also susceptible to the mechanism.
Tests on statically loaded smooth samples tests on statically loaded precracked samples tests using slowly straining samples more detailed information on these tests can be found in chapter 17, evaluation of stress corrosion cracking, in this book, and in ref 1. Jan 16, 2018 the failure mechanism for both fractured components a pipe and a heat exchanger tube was alkaline carbonate stress corrosion cracking. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Mechanisms of stress corrosion cracking and intergranular attack in. The mechanism of scc is shown as a simple representation in figure 1. In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal. External chloride stress corrosion cracking ecscc is a type of corrosion under insulation cui that appears in austenitic stainless steels.
Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Stress corrosion cracking is a progressive type of failure that causes cracks at stress levels well below a materials yield point. A mechanism for stress corrosion cracking of duplex stainless steels in hot alkaline environments in the presence of sulfide andor chloride was proposed. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. A further investigation of the synergistic effect of hydrogen and stress on dissolution at the cracktip is essential to determine the mechanism of nearneutral ph stress corrosion cracking of. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Control of alkaline stress corrosion cracking in pressurizedwater reactor steam generator tubing i. Stress corrosion cracking is a major issue for rcs system pipes particularly in the weld regions where it is connected to rpv nozzles through safe ends.
Mechanisms of stresscorrosion cracking asm international. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. The mechanism of aluminium corrosion in alkaline solutions. Amine cracking typically occurs on the surface and the cracks are usually radially. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Also, scc is a major issue for steam generator tube integrity in many us pwrs. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Review of carbonate stress corrosion cracking, which is administered by specific technology group stg 34, petroleum refining and gas processing, and is sponsored by stg 60, corrosion mechanisms.
Pdf stress corrosion cracking and hydrogen cracking. Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Susceptibilities to stress corrosion cracking scc of x80 pipeline steel in. Stressed areas such as heataffected zones slip, breaking the passive film and exposing bare steel, which corrodes to form cracks. Stress corrosion cracking scc is defined as the growth of cracks due to the. It is the gradual destruction of materials usually a metal by chemical andor electrochemical reaction with their environment.
It is thought that ascc is caused by a film rupture mechanism. This type of failure is known as stress corrosion cracking, often abbreviated to scc. It also excludes intercrystalline or transcrystalline corrosion, which can disintegrate an alloy without applied or residual stress. It is caused by a combination of material properties now recognized as affecting mostly high strength alloys, it occurs in part under high tensile strength and. Stress corrosion cracking international institute of. Stress corrosion cracking facts and how to reduce the risk. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Carbonate cracking more threatening at high ph and high concentrations of carbonate solutions, carbonate cracking is a form of alkaline stress corrosion cracking acscc prevalent to oil and gas. Corrosion basics, mechanism, types mechanical engineering. Amine cracking is a form of stress corrosion cracking, which is related to alkaline and carbonate stress corrosion cracking. The mechanism of stress corrosion cracking is not well understood but it is believed to be caused by stress, corrosive environments and susceptible microstructures.
Primary water stress corrosion cracking scc of reactor coolant system alloy 82182 dissimilar metal welds has been selected as the initial application for examining the feasibility of r7compatible physicsbased cumulative damage models. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. This was different from the result in an acidic soil environment observed by liu et al. Outerdiameter stress corrosion cracking odscc of alloy 600 uns n06600 tubings in steam generators of the kori1 pressurizedwater reactor pwr caused an unscheduled outage in 1994. This technical committee report is issued by nace international under the auspices of. Cracking mechanism an overview sciencedirect topics. A study on the mechanism of stress corrosion cracking of duplex. A new understanding of stress corrosion cracking mechanism of. Nace sp0403 avoiding caustic stress corrosion cracking.
Hwang 1 department of nuclear engineering, seoul national university, room 32211, 561 shinlimdong, gwanakku, seoul, 151742, korea. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. These all result in diminished mechanical properties. Alkaline carbonate stress corrosion cracking is a mechanism that has become more widely recognized in refinery service.
Marcus, 2011, corrosion mechanism in theory and practice, third. Failure analysis and remedy development studies were undertaken to avoid a recurrence. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Stress corrosion cracking scc is a progressive fracture mechanism in metals that is a result of the simultaneous interaction of a corrodent and a sustained tensile stress. Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Its very tricky to deal with since only very low levels of residual stress are required for carbonate cracking to occur. Stresscorrosion cracking scc is a cracking process that requires the simultaneous action of a corrodent and sustained tensile stress. Stress corrosion cracking the international institute of. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Zaki ahmad, in principles of corrosion engineering and corrosion control, 2006. The corrosion of pure aluminium in alkaline solution has been explored using an open circuit potential transient, potentiodynamic polarization experiment and a. The mechanism of al corrosion in alkaline solutions 1469 open circuit potential and subsequent addition of the two currents at a specified potential. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries.